全文获取类型
收费全文 | 139篇 |
免费 | 17篇 |
国内免费 | 49篇 |
专业分类
安全科学 | 14篇 |
废物处理 | 10篇 |
环保管理 | 24篇 |
综合类 | 83篇 |
基础理论 | 33篇 |
污染及防治 | 29篇 |
评价与监测 | 3篇 |
社会与环境 | 2篇 |
灾害及防治 | 7篇 |
出版年
2023年 | 8篇 |
2022年 | 1篇 |
2021年 | 4篇 |
2020年 | 3篇 |
2019年 | 10篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 9篇 |
2015年 | 9篇 |
2014年 | 8篇 |
2013年 | 25篇 |
2012年 | 17篇 |
2011年 | 11篇 |
2010年 | 3篇 |
2009年 | 16篇 |
2008年 | 4篇 |
2007年 | 5篇 |
2006年 | 9篇 |
2005年 | 6篇 |
2004年 | 5篇 |
2003年 | 11篇 |
2002年 | 4篇 |
2001年 | 5篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1988年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有205条查询结果,搜索用时 15 毫秒
51.
Akinpelu K Babayemi Okechukwu D Onukwuli Akindele O Okewale Olusola A Adesina 《环境质量管理》2019,28(3):55-62
Activated carbon was prepared from coconut shell, an agricultural waste, for the removal of phosphorus from synthetic phosphorus‐containing wastewater. The activated carbon obtained from the coconut shell was characterized using Fourier‐transform infrared (FTIR) spectroscopy. Batch mode experiments were conducted to study the effects of pH, particle size, adsorbent dosage, and sorption time on the adsorptive potential of the prepared activated carbon. Response surface methodology was employed to study the interactions among the variables and to optimize the process conditions for the maximum removal of phosphorus using the coconut shell–based activated carbon (CNS). The characterization results from the FTIR showed the presence of variety of functional groups, such as ?OH, ?NH, C=O, C?H, C?N, CH3, and CH2, which explains the CNS's improved adsorption behavior on the colloidal particles. A maximum performance of 95.22% was obtained for CNS at the optimum conditions of adsorbent dosage = 1,000 milligrams (local variable), pH 2 (local variable), particle size = 0.2 millimeters (local variable), and sorption time = 4.2 hours (global variable). 相似文献
52.
53.
54.
以核桃壳为原料,钛铁矿为造孔剂,制备钛铁矿造孔核桃壳基活性炭。实验结果表明:在氯化锌浓度为3mol/L、碳化时间为40min、碳化温度为400℃、钛铁矿加入量为5%的条件下,制得的钛铁矿造孔核桃壳基活性炭对苯酚、碱性品红、Pb2+的吸附量分别达到了156.80,181.35,35.84mg/g,比核桃壳活性炭分别提高了25.84%,18.59%,19.10%;钛铁矿作为造孔剂制备活性炭,可以降低碳化温度和缩短碳化时间,且对活性炭中孔的形成起促进作用,有利于对大分子物质和重金属的吸附去除。 相似文献
55.
The occurrence of antibiotics in the environment has recently raised serious concerns regarding their potential threat to human health and aquatic ecosystem. A new magnetic nanocomposite, Fe304@C (Fe304 coated with carbon), was synthesized, characterized, and then applied to remove five commonly-used sulfonamides (SAs) from water. Due to its combinational merits of the outer functionalized carbon shell and the inner magnetite core, Fe3O4@C exhibited a high adsorption affinity for selected SAs and a fast magnetic separability. The adsorption kinetics of SAs on Fe304 @ C could be expressed by the pseudo second-order model. The adsorption isotherms were fitted well with the Dual-mode model, revealing that the adsorption process consisted of an initial partitioning stage and a subsequent hole-filling stage. Solution pH exerted a strong impact on the adsorption process with the maximum removal efficiencies (74% to 96%) obtained at pH 4.8 for all selected SAs. Electrostatic force and hydrogen bonding were two major driving forces for adsorption, and electron-donor-acceptor interactions may also make a certain contribution. Because the synthesized Fe304@C showed comprehensive advantages of high adsorptivity, fast magnetic separability, and prominent reusability, it has potential applications in water treatment. 相似文献
56.
57.
58.
波纹拱壳屋顶是一种新型的大跨轻钢结构。由于其造价低、施工期短 ,在国内已得到大规模的应用。1996年起 ,我国有几十个大跨波纹拱壳屋顶由于大风或大雪而相继发生坍塌事故 ,这类伤亡事故引起了业界的高度重视。笔者从波纹拱壳屋顶的设计理论、成型工艺、施工工艺、材质等几个方面探讨了波纹拱壳屋顶发生坍塌的原因 ,分析了影响波纹拱壳屋顶安全性能的几个主要因素 ,还提出了防止该结构倒塌的安全改进措施 相似文献
59.
近江牡蛎等7种养殖鱼虾贝类参照基因β-肌动蛋白cDNA序列的克隆与比较分析 总被引:3,自引:0,他引:3
为进一步研究水产养殖动物功能基因的表达调控,采用RT-PCR及RACE法,分离、克隆了近江牡蛎(Crassostrea ariakensis)肝脏β-肌动蛋白基因cDNA全序列.结果表明,近江牡蛎β-肌动蛋白基因cDNA全长1343bp,其中5′、3′非翻译区(UTR)分别长68bp、144bp,开放阅读框(ORF)为1131bp,编码376个氨基酸.实验同时成功获得了中华圆田螺(Cipangopaludina cahayensis)、日本沼虾(Macrobrachium nipponensis)、斑鳢(Channa maculata)、胡子鲶(Clarias fuscus)、鳙鱼(Aristichthys nobilis)、鲮鱼(Cirrhinus molitorella)6种重要淡水养殖动物肝脏β-肌动蛋白基因cDNA的核心序列及氨基酸序列.所获基因与其它动物类群的β-肌动蛋白基因氨基酸同源性高达96%以上,表明软体类、节肢类、鱼类、两栖类、鸟类和哺乳类等不同类群动物β-肌动蛋白基因在生物进化过程中高度保守.系统发育分析显示软体类、节肢类、鱼类、两栖类、鸟类和哺乳类脊椎动物β-肌动蛋白分类与传统的分类基本一致. 相似文献
60.
Transesterification of a mixture of vegetable oils with methanol using metal oxide catalysts derived from snail shell (SS) for biodiesel production was investigated. The metal oxides obtained from calcined snail shells in the temperature range of 650°–950 °C and modified by loading different potassium salts were used as a catalyst in the process. The catalysts were characterized by FT-IR, XRD, SEM-EDS, XPS and TGA. Catalytic activities of developed catalysts were also tested by Hammet indicator method and ion exchange method. The best calcination conditions were observed at 850°C for 4 hours based on biodiesel yield. The KF loaded snail shell gave highest biodiesel yield of 98 ± 1% in a batch reactor with highest basicity (15.9 mmoles/g) and basic strength measured by Hammet method. The optimized reaction conditions were: reaction temperature 65°C, reaction time 3 hours, methanol to oil molar ratio 9:1 and catalyst concentration 3wt%. Leaching and reusability tests confirm the stability of the catalyst as it encounters only 3% of leaching and small changes in catalytic activity up to five runs in terms of biodiesel yield. 相似文献